The best option for transfer from Ljubljana Airport to the city center and back is Prevozi Markun (www.markun-shuttle.com) or GoOpti (www.goopti.com) Shuttle. The shuttle driver waits for you at the arrivals terminal and takes you to your hotel. The price is 9 Euros per person. It may happen that you will have to wait up to 20 minutes for other passengers to arrive. There is also bus service at the airport, for the schedule check www.lju-airport.si/en/passengers-and-visitors/getting-here/bus
If you are arriving at some other airport (Trieste, Venice, Zagreb, Klagenfurt, ...), you can use transfer service GoOpti (www.goopti.com) as well.
The following link will show the city map:
Additional information about Slovenia and Ljubljana can be found at the following webpages:
https://www.visitljubljana.com/en/visitors/
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